When is vapor pressure measured
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Agustian , Xinchi Zhang. A Framework for Learning in the Chemistry Laboratory. Israel Journal of Chemistry , 59 , Ranjbar-Naeini , A. Barandak , MH. Tahmasebi , A. This escaping process is evaporation. When a liquid evaporates in a closed container, the escaped gas moeclues cannot go away, and thus they produce a vapor pressure above the liquid. As the container stands, the number of molecules entering the vapor increases, and some of the gas molecules return to the liquid.
This returning process is condensation. Eventually the rate of evaporation equals the rate of condensation. The container is now saturated with vapor and a dynamic equilibrium exists between the gas and the liquid. This saturated vapor pressure of a liquid is its vapor pressure. An increase in the temperature of a contained liquid increases the vapor pressure because the molecules in the warmed liquid have increased kinetic energy.
When the vapor pressure of a liquid is increased to the atmospheric pressure by heating, it boils. This demonstration can also be usde to explain Roult's law - colligative property. When a non-volatile solute is added to a pure liquid, the entropy of the system is increased by mixing and the rate of evaporization is decreased, leading to the vapor pressure lowering. This tendecy is proportional to the molality of a solution. That is the Roult'law. Measuring Vapor Pressure of Liquids.
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